PAHs Tabular Elution Order
PAHs (Tabular Elution Order Data)
DB-35ms PAH Conditions
| Column | DB-35ms |
| 30 m x 0.25 mm ID, 0.25 m film | |
| P/N: 122-3832 | |
| Carrier | Helium, 1.0 mL/min (38 cm/sec), constant flow |
| Oven |
110 °C initial temperature (no hold), |
| Injector |
Cool-on-column, oven-track mode 1 L injection |
| Detector |
5973 Inert MSD, 280 °C transfer line, |
Table Credits
Agilent wishes to thank the following individuals for graciously providing this chromatogram: Louis Vromet, Serge Moore and Sylvain Levesque from the Centre d Expertise en Analyse Environnementale du Qu‚bec, MinistŠre de l Environnement du Qu‚bec, St-Vincent-de-Paul (Laval), Qu‚bec, Canada.
This data does not constitute an endorsement or recommendation by Louis Vromet, Serge Moore and Sylvain Levesque nor the Centre d Expertise en Analyse Environnementale du Qu‚bec, MinistŠre de l Environnement du Qu‚bec.
| Name | RT | m/z 1 | m/z 2 |
| naphthalene-d8 | 4:30 | 136.11 | 134.10 |
| naphthalene | 5:27 | 128.06 | 127.06 |
| 2-methylnaphthalene | 7:19 | 142.08 | 141.07 |
| 1-methylnaphthalene | 7:47 | 142.08 | 141.07 |
| 2-chloronaphthalene | 9:14 | 162.02 | 164.02 |
| 1-chloronaphthalene | 9:20 | 162.02 | 164.02 |
| 1,3-dimethylnaphtalene | 9:46 | 156.09 | 155.09 |
| acenaphthylene | 10:34 | 152.06 | 151.06 |
| acenaphthene-d10 | 10:49 | 164.14 | 162.13 |
| acenaphthene | 10:54 | 153.07 | 154.08 |
| 2,3,5-trimethylnaphthalene | 11:22 | 170.11 | 155.09 |
| fluorene | 11:50 | 166.08 | 165.07 |
| phenanthrene-d10 | 13:18 | 188.14 | 184.11 |
| phenanthrene | 13:20 | 178.08 | 176.06 |
| anthracene-d10 | 13:22 | 188.14 | 184.11 |
| anthracene | 13:24 | 178.08 | 176.06 |
| carbazole | 13:48 | 167.07 | 166.07 |
| fluoranthene-d10 | 14:54 | 212.14 | 208.11 |
| fluoranthene | 14:56 | 202.08 | 200.06 |
| pyrene-d10 | 15:20 | 212.14 | 208.11 |
| pyrene | 15:23 | 202.08 | 200.06 |
| 2-methylfluoranthene | 15:33 | 216.09 | 215.09 |
| benzo[c]phenanthrene | 17:28 | 228.09 | 226.08 |
| benzo[c]acridine | 17:36 | 229.09 | 228.08 |
| benzo[a]anthracene-d12 | 17:56 | 240.17 | 236.14 |
| benzo[a]anthracene | 18:01 | 228.09 | 226.08 |
| chrysene-d12 | 18:08 | 240.17 | 236.14 |
| chrysene | 18:14 | 228.09 | 226.08 |
| 3-methylchrysene | 19:15 | 242.11 | 241.10 |
| 2-methylchrysene | 19:26 | 242.11 | 241.10 |
| 6-methylchrysene | 19:34 | 242.11 | 241.10 |
| 5-methylchrysene | 19:36 | 242.11 | 241.10 |
| 4-methylchrysene | 19:42 | 242.11 | 241.10 |
| 1-nitropyrene | 20:19 | 247.06 | 201.07 |
| benzo[b]fluoranthene | 22:00 | 252.09 | 250.08 |
| 7,12-dimethylbenzanthracene | 22:02 | 256.13 | 241.10 |
| benzo[k]fluoranthene | 22:07 | 252.09 | 250.08 |
| benzo[j]fluoranthene | 22:10 | 252.09 | 250.08 |
| benzo[e]pyrene-d12 | 23:30 | 264.17 | 260.14 |
| benzo[e]pyrene | 23:31 | 252.09 | 250.08 |
| benzo[a]pyrene-d12 | 23:39 | 264.17 | 260.14 |
| benzo[a]pyrene | 23:46 | 252.09 | 250.08 |
| perylene | 24:17 | 252.09 | 250.08 |
| 3-methylcholanthrene | 24:59 | 268.13 | 252.09 |
| dibenzo[a,h]acridine | 28:10 | 279.10 | 277.09 |
| dibenzo[a,j]acridine | 28:23 | 279.10 | 277.09 |
| dibenzo[a,j]anthracene | 28:30 | 278.11 | 276.09 |
| dibenzo[a,h]anthracene-d12 | 29:07 | 292.20 | 288.17 |
| dibenzo[a,c]anthracene | 29:09 | 278.11 | 276.09 |
| indeno[1,2,3cd]pyrene | 29:18 | 276.09 | 274.08 |
| dibenzo[a,h]anthracene | 29:19 | 278.11 | 276.09 |
| benzo[g,h,i]perylene-d12 | 30:45 | 288.17 | 284.14 |
| benzo[g,h,i]perylene | 30:55 | 276.09 | 274.08 |
| 7h-dibenzo[c,g]carbazole | 31:38 | 267.10 | 265.09 |
| anthanthrene | 31:43 | 276.09 | 274.08 |
| dibenzo[a,e]fluoranthene | 36:47 | 302.11 | 300.09 |
| dibenzo[a,l]pyrene | 37:00 | 302.11 | 300.09 |
| dibenzo[a,e]pyrene | 38:54 | 302.11 | 300.09 |
| coronene | 39:11 | 300.09 | 298.08 |
| dibenzo[a,i]pyrene | 39:59 | 302.11 | 300.09 |
| dibenzo[a,h]pyrene | 40:32 | 302.11 | 300.09 |